I love Blender. Even though I tend to be a bit of a slacker who doesn't follow through with anything - and am a bit of an eternal hobbyist - I've been using it for about 11-12 years now and know it better than most. Before that I used Maya for ~6-7 years. It would be nice to see more people embrace Blender, so in pursuit of that, here is a bit of a link dump for handy information related to it.
Starter/general tutorial sources:
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Rigging:
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Sculpting:
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If you are set on morphing characters in Daz, but would rather use those characters within Blender for everything else:
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An alternative to Daz and MakeHuman that works directly in Blender itself via an addon:
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There is plenty more, but these are just a few things that were on the top of my head as stuff I highly suggest fairly often. I might start a new thread elsewhere to amass a more thorough collection of quality Blender related content I've come across over the years. But this ought to get you started and keep you busy for a few years the way it is, lol.