Like I said before. Settings are NOT saved in an .urm file!Yeah that's the same URM file I told you about from before, it doesn't save the settings, it only saves the other stuff like textbox.
Can you try making a URM file with the global settings after you change the opacity to 45% and the theme to vulcano?
Then share it so that I can check and let you know if it works.
Could you check which paths are shown when you press the question mark next to the save button in the save dialog?