Does Val has to be free and not enslaved? Cause the only option if i click the icon is to turn the hero chick to a bimbo, i remember one time where June entered my room with a different hair colour but that was a long time ago
Val can be in any personality AFAIK.
IIRC, the order is:
NG:
Date anyone with a specific type of hair color (let's say Sarah, who has Blue). Do at least IIRC 3 dates with her
Complete any NG+ (I recommend Bimbo World to make June a bimbo or Mysterious Book as it's fast)
NG+:
Date anyone that has a different hair color than the original hair color (let's say Kate, who has Purple)
Do at least 2 dates with new wife
Meet June in the streets (she has her original hair color IIRC)
Meet June in your room
Speak to Val in the streets (she'll tell you June's name)
Speak to Val in the streets again (she'll tell you June is hiding in the forest)
Head to the forest to speak with June
If you're on the Bimbo's Gone Wild route, June appears in the forest so you can turn her into a bimbo there.