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If Samantha introduces you as her boyfriend, you won't be able to kiss nor date her. Sam does this if you are on path A, so in order to avoid it you have to meet Emma after the wedding but before Sam dumps Ryan.
I find that Samantha path D (Revenge Path) is the only way to get both Emma & Samantha.
Because you need (handcuffs) >= 75 to get [Samantha will accept a non exclusive relationship.]
And you can completely bypass "Talk with Samantha" [
Prerequisites: Emma (heart) >= 60, Samantha is not friendzoned, Samantha introduced you as her boyfriend.]