where do you get Valyria? Where do you farm girls?
The TLDR answer is "start a new game" you will find that in the early battles, there were a lot of girl one-of enemies that now you can capture
The relevant info is on the wiki, but since it is not concentrated, let me give it to you. From my experience there are 3 general female battle "classes": The Bandit Girl, The Punkess and the Shaana.
Of this 3, The bandit Girl is an ambush that is farmable in Marston Avenue, she comes alone with a rifle and respawns every 2-3 weeks acording to wiki (Daenerys is 1 of this)
The Shaana is a semi rare "class" that appears randomly when some chinese-like gang re-takes over one of the forts after you clear it. She usually comes with a power katana. Again, it is RARE and not at all as easy to see as the bandit girl.
So far, The Punkess only appears on quest-scripted battles, so all of the punkess are "uniques".
The Valkirya and The Ex-Gladiatrix are 2 uniques- one of a kind encounters, it means that if you dont capture them, you´ll never get them, at least for now
Which quests have girls to fight? Here is the list that I´ve compiled so far: If they have an unique name, it will be first:
* Mae -Punkess- Intro Quest from Arsen, literally your first fight you can get her on day 1. ( Meaning that I´ve been dragging her ass around for almost 200 days lol)
*Talika -Shaana- 1st ever bounty: Target: Haruto Pai. You have the option to listen to them and let them go. Dont, and fight.
* Lovisa´s old Apartment "landlady"- Punkess- Doing Lovisa´s "loving" Quest, where you visit her old apartment, you encounter some unknowns. Just like Talika, If you listen to them you will reach a compromise and let them go. Or you can fight, kill her family and take her as a slave.
*Zenobia- Unique- Exactly like Lovisa´s Landlady, but in "The Ring Quest" where you visit "Luckie´s" apartment. You can either threaten, bribe or fight the group in the building, this one is named "Cyber Punk Girl"
*Sex Slave Urchin from a Rap***artist on Stoke Hills (She DOESNT appear on the fight, but it is on the color description on the left, after the fight you will see that you get a female slave for free, she is EXTREMELY docile, 20 willpower of so. I Trained her and sold her as the first mission to the docks bar)
*Wolfrang Gang fight on Casey Park- Punkess (I think this is the "Jolene" you see in my pick)
*Akari Ito- Shaana- The "Boss" Of the mind controlled Space Marines you have to kill in order to invest on the Caravans on Casey Park. has the Potential to roll Extremely High on both Melee AND Range combat. Also Aria Bianchi-like Willpower. She comes with an unique Religion and her background (still incomplete) is unique, too.
*Valkirya- Unique- She appears as a fight on Marston Avenue after day 15 or so IIRC.
*Ex-Gladiatrix- Unique- In Kahill Outpost ask for a Bounty Job. She appears armed with a 50 Cal Rifle (this is the "Awil" in the pic)
And that´s it so far.
So unless you restart, you are left just with a 1-chance for Valkirya and Ex-Gladiatrix, the respawnable Bandit Girl and the very rare shaana. At least from what I´ve seen.