Yeah.
There's 4 (technically 5) humans:
* Molly: Progress Roxy's storyline and pick the correct option.
* Laura: Wait until she visits the manor's living room and then ask Jessica about her (in the kitchen)
* Renee: Wait until she leaves a message for you in Jessica's office and play that event, then ask Jessica. NOTE: If you had sex with her the first time, her daughter Julie will come with her.
* Lucille: Check the shops at night, play the event and ask Jessica.
And 2 (technically 3) fey:
* Ami: Progress the fey main story lead and pick the correct option.
* Hana: Progress the fey main story lead and pick the correct option.
Also Emma moves into the manor when you get her to 4 hearts, but she's not a side girl, she will be in the West side of the manor.